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arsenic | ahrs-nik | 4.30 barns | | pnictogen | 67 to 87 | 31.9 kJ mol-1 | Albertus Magnus | 50.0 W m-1 K-1 at 300 K for α form | 1250 | ocean | arsenikon = yellow orpiment from Greek | 4.6 × 10-6 K-1 | 27.7 kJ mol-1 | available as powder. Danger ! | not much mined as such because more than required is produced as a by-product of refining certain sulfide ores | 0.04 to 1.4 mg | 50 to 300 mg | 90000 years | arsenopyrite, conichalcite, enargite, lollingite, olivenite, orpiment and realgar | 1090 K for α form under pressure | 0.658 × 10-12 cm | | increasing with depth | 121 pm | 4S3/2 in ground state | c = 10.548 pm for β form | | 0.5 to 15 mg for a 70 kg average person depending on diet | | V | | recycled oceanic element | | 20.786 J K-1 mol-1 for gas at constant pressure of 0.1 MPa at 298.15 K | 200 pm | 15.9 cm3 for β form | a metalloid element with two main forms, grey α arsenic and β arsenic | 889 K sublimes | salts and arsine gases are very poisonous. Stimulates metabolism in small doses, but it is carcinogenic and possibly teratogenic | essential to some species including humans | 69 pm for As3+ | 26 × 10-8 Ω m at 273 K | 74.92159 in units of 12C = 12.000 | arsenopyrite, realgar and orpiment | 78 kJ mol-1 from As to As- | 7440-38-2 for Chemical Abstracts System database | 4700 kg m-3 for solid at 293 K (β form) | 125 pm | 33 | | -3.97 × 10-9 kg-1 m3 for β form | brittle for α form | Germany | 22 | 5 to 50 mg | 1.75 × 10-3 p.p.m. in deep Pacific seawater | 454.348 nm for As II | hot acids and molten NaOH, tarnishes burns in oxygen | | As | alloys, semiconductors, pesticides, wood preservatives and glass | 47000 tonnes per year for As2O3 | [Ar]3d104s24p3 in ground state | 33 | 69.7 cm2 g-1 for MoKα X-ray diffraction | 0.009 to 0.65 p.p.m. in muscle | 2.18 Pauling | metallic for α form | 15 |
boron | bohr-on | 767 barns | | atom | 8 to 13 | 538.9 kJ mol-1 | L.J. Lussac and L.J. Thenard | 27.0 W m-1 K-1 at 300 K | 1808 | ocean | buraq from Arabic | 5 × 10-6 K-1 | 22.2 kJ mol-1 | crystals, pieces or powder. Safe. | ulexite in USA, Tibet, Chile; colemanite in USA, Turkey | 1 - 3 mg | 10 - 20 g as boric acid | 1 × 107 years | borax, colemanite, datolite, kernite, ulexite | 2573 K | 0.535 × 10-12 cm | | depth indenpendent | 88 pm | 2P1/2 in ground state | a = 506.7, α = 58deg4' pm for α-B | | 18 mg for a 70 kg average person | 270 × 106 tonnes as B2O3 | III | | accumulating oceanic element | | 20.799 J K-1 mol-1 for gas at constant pressure 0.1 MPa at 298.15 K | 208 pm | 4.62 cm3 | Non-metal with several forms - the most common form is a dark amorphous powder, unreactive to water, acids and alkalis. Rare and fragile element. Nuclear reactions in stars destroy it. Most boron is created in space, by cosmic rays that smash into heavier atoms and split them. | 3931 K | boric acid and borates are poisonous, although once used in medicines | essential to plants; toxic in excess | 23 pm for B3+ | 18000 Ω m at 293 K | 10.811 in units of 12C = 12.000 | kernite, borax, ulexite, colemanite | 26.7 kJ mol-1 from B to B- | 7440-42-8 for Chemical Abstracts System database | 2340 kg m-3 for β-rhombohedral solid at 293 K | 83 pm | 5 | | -7.8 × 10-9 kg-1 m3 for solid | | Paris, France and London, England | 6 including nuclear isomers | 5 g as boric acid | 4.41 p.p.m. in seawater | 1166.247 nm for B I | metals to form borides | boron 11 | B | borosilicate glass, detergents and fire-retardants | 1 × 106 tonnes year-1 as B2O3 | [He]2s22p1 in ground state | 5 | 0.392 cm2 g-1 for MoKalpha X-ray diffraction | 0.33 - 1 p.p.m. in muscle | 2.04 Pauling | | 13 |
silicon | sil-i-kon | 0.171 barns | 39.7 GPa | atom | 24 to 34 | 383.3 kJ mol-1 | J.J. Berzelius | 148 W m-1 K-1 at 300 K | 1824 | in silicate materials such as igneous rocks | silicis = flint from Latin | 4.2 × 10-6 K-1 | 39.6 kJ mol-1 | available as powder, pieces or lumps. Safe. | talc in Austria, Italy, India, South Africa, Australia, mica in Canada, USA, India, Brazil | 18 - 1200 mg | non-toxic | 30000 years | silicates | 1683 K | 0.41543 × 10-12 cm | | increasing with depth | 117 pm | 3P0 in ground state | a = pm | 0.42 GPa | 1 g for a 70 kg average person | unlimited × 10 tonnes | IV | 113 GPa | recycled oceanic element | HF acid or hot alkali solutions by dissolving | 22.251 J K-1 mol-1 for gas at constant pressure 0.1 MPa at 298.15 K | 200 pm | 12.06 cm3 | ultrapure crystals of silicon have a blue-grey metallic sheen | 2628 K | some silicate fibres are carcinogenic such as asbestos | essential to some species and possibly to humans | 271 pm for Si4- | 0.001 Ω m at 273 K | 28.0555 in units of 12C = 12.000 | quartz, talc, mica | 133.3 kJ mol-1 from Si to Si- | 7440-21-3 for Chemical Abstracts System database | 2525 kg m-3 for liquid at 1683 K melting point | 117 pm | 14 | reduction of sand (SiO2) with carbon produces black amorphous silicon | -1.8 × 10-9 kg-1 m3 for solid | | Stockholm, Sweden | 11 including nuclear isomers | non-toxic | 4.09 p.p.m. in deep Pacific seawater | 637.136 nm for Si II | | silicon 28 | Si | semiconductors, alloys and polymers | 3.4 × 106 tonnes year-1 for metallurgical grade | [Ne]3s23p2 in ground state | 14 | 6.44 cm2 g-1 for MoKα X-ray diffraction | 100 - 200 p.p.m. in muscle | 1.90 Pauling | | 14 |
tellurium | | | | chalcogen | | | | | | | | | | | | | | | | | | | | | | | | | | | | group VI element | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | 16 |